CO/O2 assisted oxidative carbon-carbon and carbon-heteroatom bond cleavage for the synthesis of oxosulfonates from DMSO and olefins.

نویسندگان

  • Ailong Shao
  • Meng Gao
  • Songtao Chen
  • Tao Wang
  • Aiwen Lei
چکیده

Selective carbon-carbon and carbon-heteroatom bond cleavage was achieved in a one reaction system. With this strategy a novel Pd/Cu-catalyzed aerobic oxidative oxosulfonation of olefins with DMSO has been developed. Preliminary mechanistic investigations indicated that CO/O2 assisted the bond cleavage and the leaving groups from the starting materials were trapped by O2 and underwent a hydroxylation process.

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منابع مشابه

CO/O2 assisted oxidative carbon–carbon and carbon–heteroatom bond cleavage for the synthesis of oxosulfonates from DMSO and olefins† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c6sc04480h Click here for additional data file.

General information...........................................................................................S2 General procedure..............................................................................................S3 Detailed descriptions for products..........................................................................S4 Identification of by-product of diethyl (1-phenylvinyl) pho...

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عنوان ژورنال:
  • Chemical science

دوره 8 3  شماره 

صفحات  -

تاریخ انتشار 2017