CO/O2 assisted oxidative carbon-carbon and carbon-heteroatom bond cleavage for the synthesis of oxosulfonates from DMSO and olefins.
نویسندگان
چکیده
Selective carbon-carbon and carbon-heteroatom bond cleavage was achieved in a one reaction system. With this strategy a novel Pd/Cu-catalyzed aerobic oxidative oxosulfonation of olefins with DMSO has been developed. Preliminary mechanistic investigations indicated that CO/O2 assisted the bond cleavage and the leaving groups from the starting materials were trapped by O2 and underwent a hydroxylation process.
منابع مشابه
CO/O2 assisted oxidative carbon–carbon and carbon–heteroatom bond cleavage for the synthesis of oxosulfonates from DMSO and olefins† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c6sc04480h Click here for additional data file.
General information...........................................................................................S2 General procedure..............................................................................................S3 Detailed descriptions for products..........................................................................S4 Identification of by-product of diethyl (1-phenylvinyl) pho...
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ورودعنوان ژورنال:
- Chemical science
دوره 8 3 شماره
صفحات -
تاریخ انتشار 2017